{6,6′-Dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato}nickel(II) dimethyl­formamide monosolvate

نویسندگان

  • Kouassi Ayikoé
  • Ray J. Butcher
  • Yilma Gultneh
چکیده

In the title compound, [Ni(C(18)H(18)N(2)O(4))]·C(3)H(7)NO, the central Ni(II) atom is in a square-planar O(2)N(2) coordination environment. The planar Ni-salen moieties (r.m.s. deviation for the plane through the conjugated part of the Ni-salen group = 0.07 Å) form parallel stacks in the a-axis direction, with alternating Ni⋯Ni separations of 3.5339 (7) and 3.6165 (7) Å. In the crystal, there are weak inter-molecular C-H⋯O inter-actions involving the dimethyl-formamide O and phenolate O atoms.

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Aqua­chlorido{6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato-κ2 O 1,N,N′,O 1′}cobalt(III) dimethyl­formamide monosolvate

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011